- In case it hasn’t already been obvious in the last three decades, people are obsessed with him. From his highly publicized marriage to (and divorce from) Angelina Jolie to his starring roles in Mr. and Mrs. Smith and Fight Club, or his dual role as the Sexiest Man Alive, fans want to know more about this famous man. Not only does the audience like to see him on the big screen, but for years he has been talked about in Hollywood gossip (on more than one occasion). Recently, the Once Upon a Time actor in Hollywood made headlines again for his relationship with his girlfriend Ines de Ramon.